Exposure Pathways
Years ago, dig-and-haul was the common remediation solution for soils contaminated with hazardous organics or heavy metals. Our team will work with you to rapidly develop and implement an effective in situ soil remediation solution. The EPA has its own view on remediation technologies for cleaning up contaminated sites that can be reviewed at EPA.gov.
Soil remediation generally attempts to address one of three potential exposure pathways:
- Direct exposure to contaminated soils
- Inhalation exposure to contaminated vapors
- Ingestion exposure to contaminated groundwater
Direct exposure to contaminated soils
Direct exposure to contaminated soils can occur through dermal contact or ingestion of contaminated soil particles. There are several soil remediation technologies available to mitigate this exposure pathway, such as:
- Biological based remediation (bioventing)
- Physical remediation (soil vapor extraction)
- Chemical remediation (chemical oxidation such as persulfate, chemical reduction, etc.)
- Removal or isolation (excavation, in situ stabilization, engineered barriers, or a clean cover)
- Thermally enhanced remediation technologies (thermal desorption)
Depending upon the physical makeup of the existing soils, type and depth of contaminant, planned site usage, and other site factors, one or a combination of the above soil remediation options may be effective. Metals contamination will generally require removal, isolation, or redox modifications. Chlorinated or petroleum chemicals (e.g., benzene) can typically be remediated using biological, physical, or chemical technologies.
Inhalation exposure to contaminated vapors
Vapor exposure is primarily associated with workers completing subsurface work or vapor intrusion into occupied buildings. Contaminated soil vapors can originate from:
- Unsaturated soil impacts, or
- Saturated soil impacts diffusing through groundwater to the unsaturated zone
The vapor exposure pathway can be addressed through the use of an engineering control to reduce or isolate the contaminant (fans to clear the breathing space or sub slab depressurization systems for buildings) or a soil remediation technology such as:
- Biological based remediation (bioventing)
- Physical remediation (soil vapor extraction)
- Chemical remediation (chemical oxidation such as persulfate, chemical reduction, etc.)
Ingestion exposure to contaminated groundwater
Drinking water contamination often originates as soil contamination in either the unsaturated or saturated soil intervals. In some instances, groundwater contamination can be the result of non-aqueous phase liquids (NAPLs) that are held in the soil pore spaces or as free flowing plumes.
In the unsaturated interval, rainwater infiltration can dissolve and leach contaminants into the saturated zone below, resulting in impacts to groundwater above regulatory drinking standards. Contaminants with higher volatility can diffuse into soil gas, which can also migrate and adversely impact groundwater.
In the saturated interval, compounds with lower aqueous solubilities have a significant amount of their mass adsorbed to the soil particles. Therefore, it is often necessary to remediate the saturated soils to achieve groundwater drinking standards. Often, remedial designs only take into account groundwater concentrations, without fully understanding the complications associated with contaminants adsorbed onto soils. In most instances, the initial remedial effort is temporarily successful in reducing groundwater concentrations, but the contaminant mass that is adhered to the soils will slowly re-equilibrate with groundwater. The re-equilibration can result in groundwater concentrations returning to their pre-remedy levels (i.e., “rebound” effects). Compounds such as vinyl chloride and 1,4-dioxane are not readily adsorbed to soils, and are therefore mostly found dissolved in groundwater.
Remediation technologies available to mitigate this exposure pathway include:
- Biological based remediation (aerobic or anaerobic biodegradation)
- Physical remediation (air sparging coupled with soil vapor extraction)
- Chemical remediation (chemical oxidation such as persulfate, chemical reduction, etc.)
- Removal or isolation (excavation or in situ stabilization)
- Thermally enhanced remediation technologies
One of the most referenced guidance documents is USEPA’s 1996 Soil Screening Guidance which can be downloaded from here.